Recently I am researching about CROSS-COUPLING REACTIONS; FUNCTIONALIZATION; DERIVATIVES; OXINDOLES; ETHERS; BONDS; PHOTOSENSITIZERS; HYDROCARBONS; ACTIVATION; ANNULATION, Saw an article supported by the National Natural Science Foundation of China (NSFC)National Natural Science Foundation of China (NSFC) [21302101]; National Training Programs of Innovation and Entrepreneurship for Undergraduates [201810055095, 201910055087]; Chemistry College of Nankai University. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Hu, RM; Han, DY; Li, N; Huang, J; Feng, Y; Xu, DZ. The CAS is 59-48-3. Through research, I have a further understanding and discovery of Indolin-2-one. Application In Synthesis of Indolin-2-one
Presented herein is the first direct alkylation and hydroxylation reaction between two different C(sp(3))-H bonds, indolin-2-ones and alkyl-substituted N-heteroarenes, through an oxidative cross-coupling reaction. The reaction is catalyzed by a simple iron salt under mild ligand-free and base-free conditions. The reaction is environmentally benign, employs air (molecular oxygen) as the terminal oxidant and oxygen source for the synthesis of O-containing compounds, and produces only water as the byproduct.
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Reference:
Indoline – Wikipedia,
,Indoline | C8H9N – PubChem