A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 550-44-7, Name is 2-Methylisoindoline-1,3-dione, molecular formula is C9H7NO2. In an article, author is Yang, Ping,once mentioned of 550-44-7, Formula: C9H7NO2.
Pd-Catalyzed Dearomatization of Indole Derivatives via Intermolecular Heck Reactions
The Summary of main observation and conclusion Pd-catalyzed intermolecular dearomative Heck reaction of indoles with aryl iodides is described. The challenges on both reactivity and regioselectivity are addressed by the judicious regulation of the geometric and electronic properties of the substrates. An array of indoline derivatives bearing C2-quaternary center is obtained in good to excellent yields (up to 93%) with exclusive regioselectivity under operationally simple conditions. The mechanistic proposal is supported by detailed DFT calculations.
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