One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, such as the rate of change in the concentration of reactants or products with time. 161596-47-0, Name is (S)-2-(Oxiran-2-ylmethyl)isoindoline-1,3-dione, formurla is C11H9NO3. In a document, author is Jacquin-Labarre, Aurelien, introducing its new discovery. SDS of cas: 161596-47-0.
Base-Assisted Intramolecular C-N Coupling Reaction from NH2-Bound Cyclopalladated L-Phenylalanine to Indoline-2-carboxylic Acid
The deprotonative intramolecular-amination reaction of phenylalanine-derived palladacycles has been investigated to highlight a facile carbonate-assisted N-H activation before the C-N bond formation. A major counterion effect led to divergent pathways whereby the SPhos-Pd complexes with iodine, triflate, or trifluoroacetate anions were key intermediates to afford access to (S)-2-indolinecarboxylic acid derivatives.
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